SUMMARY OF PARAMETERS USED IN THE MCM
| KRO2NO | = 4.10D-12*EXP(180/TEMP) |
| KRO2HO2 | = 3.00D-13*EXP(1250/TEMP) |
| KAPHO2 | = 4.30D-13*EXP(1040/TEMP) |
| KRO2NO3 | = 2.50D-12 |
| KNO3AL | = 1.44D-12*EXP(-1862/TEMP) |
| KDEC | = 1.00D+06 |
| KFPAN : | |
|---|---|
| K0 | = 2.70D-28*(TEMP/298)@-7.1*M |
| KI | = 1.21D-11*(TEMP/298)@0.9 |
| FC | = 0.3 |
| KBPAN : | |
| K0 | = 4.90D-03*EXP(-12100/TEMP)*M |
| KI | = 3.7D+16*EXP(-13600/TEMP) |
| FC | = 0.3 ; |
| KMT01 : | |
| K0 | = 1.00D-31*(TEMP/300)@-1.6*M |
| KI | = 3.00D-11*(TEMP/300)@0.3 |
| FC | = EXP(-TEMP/1850) |
| KMT02 : | |
| K0 | = 9.00D-32*(TEMP/300)@-2.0*M |
| KI | = 2.20D-11 |
| FC | = EXP(-TEMP/1300) |
| KMT03 : | |
| K0 | = 2.70D-30*(TEMP/300)@-3.4*M |
| KI | = 2.00D-12*(TEMP/300)@0.2 |
| FC | = (EXP(-TEMP/250) + EXP(-1050/TEMP)) |
| KMT04 : | |
| K0 | = 2.20D-03*(TEMP/300)@-4.4*EXP(-11080/TEMP)*M |
| KI | = 9.70D+14*(TEMP/300)@0.1*EXP(-11080/TEMP) |
| FC | = (EXP(-TEMP/250) + EXP(-1050/TEMP)) |
| KMT05: | = 1 + ((0.6*M)/(2.652D+19*(273/TEMP))) |
| KMT06: | = 1 + (1.40D-21*EXP(2200/TEMP)*H2O) |
| KMT07 : | |
| K0 | = 7.40D-31*(TEMP/300)@-2.4*M |
| KI | = 3.20D-11 |
| FC | = 0.8 |
| KMT08 : | |
| K0 | = 2.60D-30*(TEMP/300)@-2.9*M |
| KI | = 6.00D-11 |
| FC | = 0.43 |
| KMT09 : | |
| K0 | = 1.80D-31*(TEMP/300)@-3.2*M |
| KI | = 4.70D-12 |
| FC | = 0.6 |
| KMT10 : | |
| K0 = | 5.00D-06*EXP(-10000/TEMP)*M |
| KI = | 2.60D+15*EXP(-10900/TEMP) |
| FC | = 0.6 |
| KMT11: | = K1 + K2 |
| K1 = | 7.20D-15*EXP(785/TEMP) |
| K2 | = (K3*M)/(1+(K3*M/K4)) |
| K3 | = 1.90D-33*EXP(725/TEMP) |
| K4 | = 4.10D-16*EXP(1440/TEMP) |
| KMT12 : | |
| K0 | = 4.00D-31*(TEMP/300)@-3.3*M |
| KI | = 2.00D-12 |
| FC | = 0.45 |
| KMT13 : | |
| K0 | = 1.90D-30*(TEMP/298)@-4.0*M |
| KI | = 1.00D-11*(TEMP/298)@-1.0 |
| FC | = 0.4 |
| KMT14 : | |
| K0 | = 9.00D-05*EXP(-9694/TEMP)*M |
| KI | = 1.10D+16*EXP(-10561/TEMP) |
| FC | = 0.4 |
| KMT15 : | |
| K0 | = 6.00D-29*(TEMP/298)@-4.0*M |
| KI | = 9.00D-12*(TEMP/298)@-1.1 |
| FC | = 0.7 |
| KMT16 : | |
| K0 | = 3.00D-27*(TEMP/298)@-3.0*M |
| KI | = 2.80D-11*(TEMP/298)@-1.3 |
| FC | = 0.5 |
| KMT17 : | |
| K0 | = 5.00D-30*(TEMP/298)@-1.5*M |
| KI | = 9.40D-12*EXP(-700/TEMP) |
| FC | = (EXP(-TEMP/580) + EXP(-2320/TEMP)) |
| J | L | M | N |
| J<1> | 8.978D-05 | 1.436 | 0.936 |
| J<2> | 5.219D-04 | 0.322 | 0.079 |
| J<3> | 1.057D-05 | 0.800 | 0.243 |
| J<4> | 1.108D-02 | 0.397 | 0.183 |
| J<5> | 2.669D-02 | 0.185 | 0.103 |
| J<6> | 1.853D-01 | 0.189 | 0.112 |
| J<7> | 2.484D-03 | 0.431 | 0.194 |
| J<8> | 1.037D-06 | 1.227 | 0.332 |
| J<11> | 4.866D-05 | 0.781 | 0.349 |
| J<12> | 6.790D-05 | 0.565 | 0.275 |
| J<13> | 8.443D-06 | 1.177 | 0.437 |
| J<14> | 3.169D-05 | 1.059 | 0.373 |
| J<15> | 2.964D-05 | 0.812 | 0.341 |
| J<16> | 1.779D-05 | 0.812 | 0.341 |
| J<17> | 8.394D-05 | 0.768 | 0.367 |
| J<18> | 1.096D-05 | 0.526 | 0.227 |
| J<19> | 1.096D-05 | 0.526 | 0.227 |
| J<21> | 9.269D-07 | 1.563 | 0.301 |
| J<22> | 6.591D-06 | 1.070 | 0.399 |
| J<23> | 1.769D-05 | 0.522 | 0.226 |
| J<24> | 1.769D-05 | 0.522 | 0.226 |
| J<31> | 6.828D-05 | 0.222 | 0.154 |
| J<32> | 1.030D-05 | 0.222 | 0.154 |
| J<33> | 3.887D-05 | 0.695 | 0.289 |
| J<34> | 1.524D-04 | 0.270 | 0.156 |
| J<35> | 3.276D-04 | 0.256 | 0.159 |
| J<41> | 5.797D-06 | 0.764 | 0.249 |
| J<51> | 1.748D-06 | 1.166 | 0.324 |
| J<52> | 2.113D-06 | 1.255 | 0.342 |
| J<53> | 2.772D-06 | 1.183 | 0.348 |
| J<54> | 4.518D-06 | 1.104 | 0.331 |
| J<55> | 1.221D-05 | 0.988 | 0.312 |
| J<56> | 8.198D-06 | 1.020 | 0.331 |
| J<57> | 3.797D-06 | 1.278 | 0.346 |
| H0 | = HEIGHT OF LOWER LAYER AT NIGHT |
| H | = HEIGHT OF LOWER LAYER |
THESE APPLY TO THE HETEROGENEOUS CONVERSION OF NO2 TO HONO AT THE GROUND SURFACE, A REACTION WHICH SHOULD THEREFORE ONLY TAKE PLACE IN THE LOWER LAYER