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Metal Layers
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About 50 tonnes of interplanetary dust enters the earth's atmosphere every day, at velocities ranging from 11 to 72 km
s-1. Most of this dust appears to vaporize completely, producing the layers of metal atoms such as Na and Fe that occur
globally in the upper mesosphere and lower thermosphere (between 80 and 105 km). Several metal atoms - Na, K, Fe and Ca - can be
observed by ground-based lidar (laser radar), and this has provided a great deal of information about the physics and chemistry of an
important region that forms the boundary between the atmosphere and space.
Our main contribution to this field has been to study the elementary reactions that these metals undergo in the upper atmosphere.
The resulting reaction rate coefficients and photochemical cross sections are then used to construct models. The laboratory
techniques that we use are: laser flash photolysis with detection of metallic species by laser induced fluorescence; and the fast
flow tube with detection of neutral species by LIF, and ions by mass spectrometry. For a review of these techniques, see Plane,
Chemical Reviews, 2003. Below are tables of recommended rate coefficients from our laboratory studies.
Recommended rate coefficients for metal layer modelling (pdf file: 88.9 KB)
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Layers of metal atoms in the mesosphere/lower thermosphere, observed by lidar at mid-latitude northern hemisphere
observatories
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Modelling the Fe layer at South Pole during summer

Fe ablation flux = 1.1 x 104 atoms cm-2 s-1
Uptake coefficients of Fe and Fe species on ice = 1. Plane et al., Science, 2004.
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Comparison of lidar observations of the Na and Fe layers at South Pole with the results of the Leeds metal layer model [Gardner
et al., 2005]
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For information related to this project
Go to > Mesosphere > Meteor Smoke
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